In this lecture, we use the identities we just developed to determine
the simple harmonic oscillator wavefunctions and other properties. The
approach given here is a little different from what you will see in
textbooks.
Factorizing the Hamiltonian
The SHO Hamiltonian is
Many textbooks postulate ladder operations as a "trick" solution, but if
we think of factorizing, like with polynomials, we would try
for factorizing the sum of squares. You might next ask why not factor in
the opposite order as
?
We will answer the ordering question later.
Now, when we work out the product, because they are operators, we find
an extra term from the commutator, or
So, we have
Finding energy eiegenstates
If we recall, for an eigenstate
,
we have
,
with normalized
,
then we see for this case
Hence, if we can find a state with
,
then this would be the ground state and we would have $E_{\text g s}=\frac{1}{2} \hbar
\omega_{0}$.
For now, we assume such a state exists. Later, we will see that it
does.
We next work out the intertwining relation (moving
through
.
We start by writing out the product with the raising operator on the
right, and then use the commutator to change the order of the pair of
operators on the right. So, we have
But, we have
so, we have
In words, moving the harmonic oscillator Hamiltonian past a raising
operator originally on the right, shifts the Hamiltonian by
.
We use this to find all of the hiher-energy eigenstates. Our claim is
that
is an energy eigenstate. Our proof just uses the intertwining
relation.
Proof:
So
We also use this to normalize the energy eigenstate. To do this, we
identify an
term in the center of the string of operators in the norm. We replace it
by the Hamiltonian, and then use intertwining to evaluate it against the
state on the right. We have
Repeat
more times:
So
This may not look like what you are used to. It is conventional to
redefine the operators via
Then,
Wavefunctions
Next up, we calculate the wave function. Recall, the eigenstate of
position satisfies
which is an operator acting on a state giving us a number times that
state.
Claim:
Proof:
But,
So it is an eigenfunction!
The operator
is called the translation operator.
Before we calculate the wavefunction, it is worthwhile to talk about
what it really is. The wavefunction is constructed by the overlap of two
eigenfunctions from non-commuting operators. We should not think of this
as a physical state the particle is in inbetween measurements. It is
instead a calculational tool used to determine the results of
experiments. Oftentimes, conventional QM instruction overemphasizes the
importance of the wavefunction in coordinate space. You should not. We
can interpret the overlap in two ways. For example
can be thought of as the probability amplitude to find a particle that
has energy
to be found in the region near
(we assume the energies are nondegenerate for simplicity here).
Similarly, the probability amplitude (technically the complex conjugate
of the probability amplitude) to find a particle located near
to have energy
.
It is important to note that
so the probabilities of both statements are the same.
It is easy to overemphasize the importance of
,
even though we can also find
and other wavefunctions. When we look at this from an operator
perspective, we will see that we can employ translation to relate the
amplitude at the origin to the ampitude anywhere else. Amazingly, the
results come entirely from operator algebra and the fact that
.
In particular, we do not need the Schrodinger equation or any other
differential equation to tell us how to determine the wavefunction. It
follows from the properties of the ground state and the ladder
operators. This holds not just for the simple harmonic oscillator, but
we will see it holds for all solvable problems later in the
course!
Now we calculate the wave function of the simple harmonic oscillator in
coordinate space:
But,
So, the operator
.
The question we now have is how do we use these operators to get the
wavefunction? We only know two things about the states
This means
and
These relations ane very important. Always look for such annihilation
relations in your work!
This then leads to a potential strategy to simplify the matrix element
that gives the wavefunction. We need to convert
into some kind of
.
Recalling that
and
tells us we should try the following:
1.) split up
correction terms
2.) move
to the right until it disappears when it hits
3.) replace it by
4.) move to the left until next to
5.) bring into the same exponent
correction terms
6.) operate onto
where
This will get rid of the full exponential form. Then we need to
determine how to deal with the rest of the expression. To do that we
work again with the same facts
and use them to simplify until we get the final wavefunction.
Now, we go through the technical details carefully.
Recall as well
,
so use BCH
Here,
.
So
Recall:
But,
, so
Lets look at
and
first:
We will use “add zero” to
convert the raising operator into an operator proportional to a position
operator via
.
So, we have
Define
.
We just showed that
from our calculations of
and
.
We now find a recurrence relation for general
.
We first split off one factor in the matrix element to the left, and
rework it as we did for the first excited state:
But,
since
and
So
This, combined with the
and
values already found are the recurrence relations for the Hermite
polynominals, summarized in the following table.
0 |
1 |
1 |
|
2 |
|
3 |
|
4 |
|
5 |
|
Note, this is the physicist’s convention. Mathematicians use a
different one.
The last thing we do is normalize the wavefunction. This requires us to
normalize just the ground state, because we have otherwise been working
with normalized states.
Uncertainty
Everything is done algebraically and comes from operators! No series
solutions of differential equations!
We end by examining uncertainty
The uncertainty is minimal for the ground state but grows with
.